They met when they started filming their movie together "Mr and Mrs Smith", but she insists that they were "only friends" until after Brad had split up with Jennifer.
Speaking to Vogue magazine, Angelina said:
QUOTE
"I think we were the last two people who were looking for a relationship. I certainly wasn't. I was quite content to be a single mom. I didn't know much about exactly where Brad was in his personal life. But it was clear he was with his best friend, someone he loves and respects."
They now have two adopted children together, and Angelina gave birth to a daughter (Brad's) earlier this year. But it's well known that they are in no rush to get married. I remember Brad saying that they would only marry once everyone was able to legally marry in America.
Angelina also said she'd like to meet up with Jennifer to sit down and just talk - but only if Jennifer suggested it. I would pay to be able to watch that.